Allyl alcohol CAS 107-18-6
This article provides a comprehensive overview of the global landscape of industrial hydroformylation technology providers and their associated processes. The key points are as follows:
- Overall Landscape: The global industrial hydroformylation process technology is highly concentrated, primarily mastered by large international chemical corporations and licensors, with a stronghold by European and American companies for the production of monohydric alcohols (like butanol, octanol, and isononanol).
- Major Technology Providers and Characteristics:
- Key Players: The Davy Process Technology and Dow Chemical joint venture, Germany’s BASF, and the U.S.’s ExxonMobil are significant technology holders.
- Licensing Models: Providers have different policies: some allow technology transfer (e.g., Davy/Dow, Eastman, Mitsubishi), some only license via joint ventures (e.g., BASF, Oman, Evonik), and one does not transfer its technology (ExxonMobil).
- Technology Distribution by Product Chain:
- Hydroformylation of Mono-olefins: Primarily for producing monohydric alcohols. Multiple companies possess the technology, with Davy/Dow and ExxonMobil capable of producing nearly the full range of linear alcohols.
- Lower Olefins:
- Butanol/Octanol (Butyraldehyde Process): The core process involves propylene hydroformylation. The Davy/Dow technology is the most widely licensed globally. Process selectivities are similar; the main differences lie in reactor and flow-sheet design.
- 2-Propylheptanol: Production follows a process similar to isooctanol. Key licensors include BASF and Eastman.
- Higher Olefins:
- Isononanal/Isononanol: Technologies are divided into low-branched and high-branched types. Low-branched technology is held by BASF, ExxonMobil, Davy/Dow, etc.; high-branched technology is mainly owned by Japan’s Kyowa Hakko. The article cites BASF’s joint venture in Maoming and Qixiang Tengda’s planned project as application examples.
- Catalyst Differences: For long-chain olefin hydroformylation, most licensors use cobalt-based catalysts requiring harsh conditions, while Davy/Dow employs a ligand-free rhodium catalyst, enabling milder reaction conditions.
- 1,4-Butanediol (1,4-BDO):
- The hydroformylation route for BDO is mainly controlled by LyondellBasell (originally from Kuraray) and Taiwan’s Dairen Chemical.
- Their processes differ in the initial method for producing allyl alcohol, the key intermediate. However, the competitiveness of this route has been challenged by the rapid expansion of the lower-cost acetylene-based (Reppe) process, particularly in China.
| ACF Chemical Co., Ltd. Athena phone/whatsapp：008613805212761 email：ceo@acfchemical.com website： https://acfchemical.com No. 45 Pengwan Road, Qianwan Bonded Port Area, Qingdao Area, China (Shandong) welcome to vist our factory. sample is free ACF Chemical Qingdao Co., Ltd. was established in 1987. the company has over decades of experience in the production of methacrylate and acrylate series products, as well as high-efficiency polymerization inhibitors and rubber and plastic antioxidant series products. The company’s leading products are high-efficiency polymerization inhibitor series products, with an annual production capacity of 1,000 tons of tert-butylhydroquinone (TBC), 800 tons of polymerization inhibitor TH-701, 500 tons of polymerization inhibitor TH-A294, 500 tons of polymerization inhibitor TH-100BE, 500 tons of phenothiazine, and 200 tons of hydroquinone. | |
| 2-Ethylhexyl nitrate | 27247-96-7 |
| Toluenesulfonamide(0/PTSA) | 1333-07-9 |
| LABSA (Linear-Alkylbenzenesulfonic Acid) | 27176-87-0 |
| MMT Methylcyclopentadienyl manganese tricarbonyl | 12108-13-3 |
| C12/18 TERTIARY AMINE(MB) | 68391-04-8 |
| Alkyl (C12-C14) Glycidyl Ether (AGE) | 68609-97-2 |
| NMA(N-methylaniline) | 100-61-8 |
| N-ethylaniline | 103-69-5 |
| C12-14-alkyldimethylamines | 84649-84-3 |
| Aniline | 62-53-3 |
| TETA ( Triethylene Tetraamine ) | 112-24-3 |
| 2EH(2-Ethylhexylamine) | 104-75-6 |
| Sodium Lauryl Ether Sulfate (SLES) | 68585-34-2 |
| Titanium dioxide powder coating, paint grade. | |
| 1-Propene, 2-methyl-, homopolymer, hydroformylation products , reaction products with ammonia | 337367-30-3 |
| PEG-40 Castor Oil (Castor oil 40 EO, Castor oil ethoxylated 40 EO) | 61791-12-6 |
| Hydrogenated PEG-40 Castor Oil (Hydrogenated castor oil 40 EO, hydrogenated castor oil ethoxylate 40 EO) – CAS 61788-85-0 | 61788-85-0 |
| Ethoxylated cocoamine EO 2 (PEG-2 cocoamine) – CAS 61791-14-8 | 61791-14-8 |
| Hydrogenated Tallow Amine ethoxylate EO 8 (PEG-8 Hydrogenated Tallow Amine) – CAS: 61791-26-2 | 61791-26-2 |
| Phenyl Glycidyl Ether | 122-60-1 |
| Neopentane Glycol Diglycidyl Ether | 17557-23-2 |
| Benzyl Glycidyl Ether | 89616-40-0 |
| Diethylene Glycol Diglycidyl Ether | 39443-66-8 |
| Butyl glycidyl ether | 2426-08-6. |
| HydrogenatedTallowAmine | 61788-45-2 |
| Dodecyltrimethylammoniumbromide | 1119-94-4 |
| Didodecyldimethylammoniumbromide | 3282-73-3 |
| Dioctyldimethylammoniumbromide | 3026-69-5 |
| Sodium Dimethyl Dithiocarbamate (SDD) | 128-04-1 |
| Potassium Dimethyl Dithiocarbamate (KDD) | 128-03-0 |
| Boron Trifluoride Etherate | 109-63-7 |
| 3-Glycidoxypropyltrimethoxysilane | 2530-83-8 |
| *MTHP – Methyl Tetra Hydro Pyran | 4717-96-8 |
| 2-(2-Methoxyethoxy)ethanol | 111-77-3 |
| HYDROQUINONE MONOMETHYL ETHER | 150-76-5 |
| MONO ISOPROPYLAMINE | 75-31-0 |
| Isopropyl Acetate (IPAC) | 108-21-4 |
| Antioxidant 24 | ANGCHEN Co., Ltd. Rm B-1803,818 North Xingyuan Road,WuXi,China P.C.: 214005 TEL : +86-510-83751665 +86-510-82327577 FAX : +86-510-82328286 E-mail : sales@angchenchem.com URL : www.angchenchem.com |
| PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE （PMA) | 108-65-6 |
| PROPYLENE GLYCOL MONOMETHYL ETHER (PM) | 107-98-2 |
| DIPROPYLENE GLYCOL DIMETHYL ETHER (DPDM) | 111109-77-4 |
| DIPROPYLENE GLYCOL MONOMETHYL ETHER ACETATE （DPMA） | 88917-22-0 |
| POLY(VINYL CHLORIDE-CO-VINYL ACETATE) | 9003‑22‑9 |
| Dimethyl terephthalate (DMT) | 120-61-6 |
| 2-3 Epoxypropyl Neodecanoate | 26761-45-5 |
| 2-Ethylhexyl Acrylate (2-EHA) | 103-11-7 |
| 12-Hydroxystearic Acid (12-HSA) | 106-14-9 |
| Hexahydrophthalic anhydride (HHPA) | 85-42-7 |
| Allyl alcohol | 107-18-6 |
| N,N-Dimethyl-n-octylamine | 7378-99-6 |
| N,N-Dimethyldecylamine | 1120-24-7 |
| N,N-Dimethyldodecylamine | 112-18-5 |
| N,N-Dimethyltetradecylamine | 112-75-4 |
| N,N-Dimethylhexadecylamine | 112-69-6 |
| N,N-Dimethyloctadecylamin | 124-28-7 |
| N,N-Dimethyl-C12-14-alkylamine | 68439-70-3 |
| DMA12/18 | 68391-04-8/61788-93-0 |
| N-Coconut-1,3-propyl diamine | 61791-63-7 |
| N-Tallowalkyl 1,3-propanediamines DAT | 61791-55-7 |
| Dodecyl trimethyl ammonium chloride | 112-00-5 |
| N-Hexadecyltrimethylammonium chloride | 112-02-7 |
| Octadecyl trimethyl ammonium chloride | 112-03-8 |
| Dioctyldimethylammonium chloride | 5538-94-3 |
| MT(M-Toluidine) | 108-44-1 |
| PT(P-Toluidine) | 106-49-0 |
| O-Toluidine OT | 95-53-4 |
| C16-18-alkyldimethyl Octadecyl/Hexadecyl dimethylamines | 68390-97-6 |
| Octadecyl/behenyl dimethylamines | 124046-42-0 |
| N-3-Laurylamidopropyl dimethylamine | 3179-80-4 |
| N-3-(Hydrogenated cocoamido)propyl dimethylamines | 288095-05-6 |
| 1,8-DIAZABICYCLO[5.4.0]UNDEC-7 | 57671-19-9 |
| DIETHYLPHENYL ACETAMIDE (DEPA) | 84-66-2 |
| 3-(2-ETHYLHEXYLOXY) PROPYLAMIN | 5397-31-9 |
| LS 944 | 70624-18-9 |
| LS 770 | 52829-07-9 |
| LS 2020 | 192268-64-7 |
| LS 123 | 129757-67-1 |
| LS 3853 | 167078-06-0 |
| LS 610 | 106990-43-6+70198-29-7 |
| UV P | 2440-22-4 |
| UV 2 | 65816-20-8 |
| UV 99-2 | 127519-17-9 |
| UV 234 | 70321-86-7 |
| UV 327 | 3864-99-1 |
| UV 360 | 103597-45-1 |
| UV 928 | 73936-91-1 |
| UV 1164 | 2725-22-6 |
| 2-Hydroxyl ethyl acrylate; HEA | 818-61-1 |
| Hydroxy propyl acrylate; HPA | 25584-83-2 |
| Benzyl Triethyl Ammonium Chloride | 56-93-9 |
| Benzyltriethylammonium bromide | 56-37-1 |
| Benzyltributylammonium bromide | 23616-79-7 |
| Tetrabutylammonium bromide | 37451-68-6 |
| Benzyltrimethylammonium bromide | 5350-41-4 |
| Benzyltributylammonium chloride | 5197-95-5 |
| Tetrabutylphosphonium bromide | 3115-68-2 |
| Methyltriphenylphosphonium bromide | 1779-49-3 |
| 4-dimethylaminopyridine | 1122-58-3 |
| Tetrabutylammonium iodide | 311-28-4 |
| Tetraethyl ammonium bromide | 71-91-0 |
| Triphenylphosphine | 603-35-0 |
| Potassium Persulfate | 7727-21-1 |
| Triphenylethyl phosphorus bromide | 1530-32-1 |
| 1, 2-Bis (diphenylphosphino) Ethane | 1663-45-2 |
| 1,3-Bis(diphenylphosphino)propane | 6737-42-4 |
| 1,5-Bis(diphenylphosphino)pentane | 2 7721-02-4 |
| (R)-(+)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl | 76189-55-4 |
| (R)-(+)-(1,1′-binaphthalene)-2,2′-diol | 18531-94-7 |
| [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride | 15629-92-2 |
| Minodronic Acid | 155648-60-5 |
| Nitrilotriacetic acid | 139-13-9 |
| n-Propyl acrylate | 925-60-0 |
| N-(Hydroxymethyl)acrylamide; NMA | 924-42-5 |
| N,N’-Methylenebisacrylamide; MBA | 110-26-9 |
| N,N-Dimethylacrylamide; DMAA | 2680-03-7。 |
| N,N-dimethyldocosylamine | 21542-96-1 |
| N-Methyldioctylamine | 4455-26-9 |
| N-methyldidodecylamine | 2915-90-4 |
| N-3-Oleylamidopropyl dimethylamine | 109-28-4 |
| N-3-Erucylamidopropyl dimethylamine | 60270-33-9 |
| N-Oleyl 1,3-propanediamine | 7173-62-8 |
| N-tallow alkyltripropylenetetra | 68911-79-5 |
| N-[3-(isodecyloxy)propyl]propane-1,3-diamine | 72162-46-0 |
| N-Methyldiethanolamine | 105-59-9 |
| N,N-dimethylcyclohexylamine | 98-94-2 |
| N,N,N’-trimethylamino-N’-ethylethanolamine | 2212-32-0 |
| N,N-Dimethylethanolamine | 108-01-1 |
| N,N’-1,3-Phenylene bismaleimide | 3006-93-7 |
| N,N’-4,4′-Diphenylene-Bismalemide | 13676-54-5 |
| N-Cyclohexyl maleimide | 1631-25-0 |
| N-Phenyl maleimide | 941-69-5 |
| N-benzyl maleimide | 1631-26-1 |
| N,N-Diethylaniline | 91-66-7 |
| N,N-DIMETHYL -P-TOLUIDINE | 99-97-8 |
| DMA(N,N-dimethylaniline) | 121-69-7 |
| NDPT(N,N-dihydroxyethyl-p-toluidine) | 3077-12-1 |
| 3-Diethylaminophenol | 91-68-9 |
| Diethanolamine | 111-42-2 |
| N,N-Dimethylbenzylamine | 103-83-3 |
| Trifluoromethanesulfonic acid | 1493-13-6 |
| p-Terphenyl | 92-94-4 |
| MethylEthylKetone | 78-93-3 |
| 1-Butanol | 71-36-3 |
| 2-Naphthol | 135-19-3 |
| N,N-Diethylhydroxylamine | 3710-84-7 |
| N,N-diethyl-m- toluamide DEET | 134-62-3 |
| Oleic acid | 112-80-1 |
| POLY(VINYL METHYL ETHER) | 9003-09-2。 |
| Triethanolamine | 102-71-6 |
| Bis(2-ethylhexyl)amine | 106-20-7 |
| Cocoamine | 61788-46-3 |
| Diethylaminoethanol | 100-37-8 |
| N,N-Dimethylcapramide | 14433-76-2 |
| N,N-Dimethylethylamine | 598-56-1 |
| Morpholine | 110-91-8 |
| Dichloroacetic acid | 79-43-6 |
| 819；Phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide | 162881-26-7 |
| M-tolyl diethanolamine (MTDA) | 91-99-6 |
| P-Tolyl Diethanolamine (PTDA) | 3077-12-1. |
| Dimethyl Thio Toluene diamine (DMTDA) | 106264-79-3 |
| Dimethyl P-Toluidine (DMPT) | 99-97-8 |
| Methyl-N-hydroxyethyl-p-toluidine (MHPT) | 2842-44-6 |
| Diisopropanol Para Toluidine (DIPT) | 38668-48-3 |
| Sodium Laureth Sulfate | 9004-82-4 |
